Geraud Dubois  Geraud Dubois photo       

contact information

TA to VP & Lab Director, IBM Research - Almaden
Almaden Research Center, San Jose, CA, USA
  +1dash408dash927dash1584

links

Professional Associations

Professional Associations:  International Sol-Gel Society  |  Materials Research Society (MRS)

more information

More information:  Stanford Materials Science and Engineering Department


2016

Carbon-bridge incorporation in organosilicate coatings using oxidative atmospheric plasma deposition
Linying Cui, Geraud Dubois, Reinhold Dauskardt
ACS Applied Materials and Interfaces8, 1309-1318, 2016

Fundamental limits of material toughening in molecularly confined polymers
Scott G. Isaacson, Krystelle Lionti, Willi Volksen, Teddie P. Magbitang, Yusuke Matsuda, Reinhold H. Dauskardt & Geraud Dubois
Nature Materials15, 294-298, 2016

Combined influence of pore size distribution and surface hydrophilicity on the water adsorption characteristics of micro-and mesoporous silica
Sarmenio Saliba, Patrick Ruch, Willi Volksen, Teddie P Magbitang, Geraud Dubois, Bruno Michel
Microporous and Mesoporous Materials226, 221-228, 2016


2015

Selective Deposition of Compositionally Graded Hybrid Adhesive Films
Marta Giachino, Brian L Watson, Geraud Dubois, Reinhold H Dauskardt
Advanced Materials Interfaces2, 1500262, 2015

The efficacy of post porosity plasma protection against vacuum-ultraviolet damage in porous low-k materials
K Lionti, M Darnon, W Volksen, T Magbitang, G Dubois
Journal of Appplied Physics117, 113303, 2015

Scratch-resistant sol gel coatings on pristine polycarbonate
Nicolas Le Bail, Krystelle Lionti, Stphane Benayoun, Sophie Pavan, Leslie Thompson, Christel Gervais, Graud Dubois, Brangre Toury
New Journal of Chemistry39, 8302-8310, 2015

Toward Successful Integration of Porous Low-k Materials: Strategies Addressing Plasma Damage
Krystelle Lionti, Willi Volksen, Teddie Magbitang, Maxime Darnon, Geraud Dubois
ECS Journal of Solid State Science and Technology 4(1), N3071--N3083, The Electrochemical Society, 2015

Molecular Design for Moisture Insensitivity of Compositionally Graded Hybrid Films
Marta Giachino, Geraud Jean-michel Dubois, Reinhold H Dauskardt
ACS Applied Materials \& Interfaces, ACS Publications, 2015


2014

The effect of cross-contamination in the sequential interfacial polymerization on the RO performance of polyamide bilayer membranes
Young-Hye La, Jacquana Diep, Radwan Al-Rasheed, Majed Nassar, E Idil Mouhoumed, Anthony Szymczyk, Geraud Dubois
Journal of Membrane Science466, 348--356, Elsevier, 2014

Highly Transparent Multifunctional Bilayer Coatings on Polymers Using Low-Temperature Atmospheric Plasma Deposition
Linying Cui, Krystelle Lionti, Alpana Ranade, Kjersta Larson-Smith, Geraud Jean-michel Dubois, Reinhold H Dauskardt
ACS nano 8(7), 7186--7191, ACS Publications, 2014



2013

Comparative Nanomechanical Study of Multiharmonic Force Microscopy and Nanoindentation on Low Dielectric Constant Materials
Katharine Walz, Robin King, Willi Volksen, Geraud Dubois, Jane Frommer, and Kumar Virwani
Scanning Probe Microscopy in Industrial Applications: Nanomechanical Characterization, pp. 302, D. Yablon, Editor, Wiley, 2013

Independent control of adhesive and bulk properties of hybrid silica coatings on polycarbonate
Krystelle Lionti, Linying Cui, Willi Volken, Reinhold H Dauskardt, Geraud Dubois, Berangere Toury
ACS Applied Materials & Interfaces 5(21), 11276-11280, ACS Publications, 2013

Heterogeneous solution deposition of high-performance adhesive hybrid films
Marta Giachino, Geraud Dubois, Reinhold H Dauskardt
ACS Applied Materials & Interfaces 5(20), 9891-9895, 2013

Improved adhesion of dense silica coatings on polymers by atmospheric plasma pretreatment
Linying Cui, Alpana N Ranade, Marvi A Matos, Geraud Dubois, Reinhold H Dauskardt
ACS Applied Materials & Interfaces 5(17), 8495-8504, 2013

Enhanced Desalination Performance of Polyamide Bi-layer Membranes Prepared by Sequential Interfacial Polymerization
Young-Hye La, Jacquana Diep, Radwan Al-Rasheed, Dolores Miller, Leslie Krupp, Geoffrey M Geise, Ankit Vora, Blake Davis, Majed Nassar, Benny D Freeman, others
Journal of Membrane Science437, 33-39, Elsevier, 2013

Investigation of plasma etch damage to porous oxycarbosilane ultra low-k dielectric
R. L. Bruce, S. Engelmann, S. Purushothaman, W. Volksen, T. J. Frot, T. Magbitang, G. Dubois, M. Darnon
Journal of Physics D-Applied Physics 46(26), 2013

Impact of low-k structure and porosity on etch processes
Maxime Darnon, Nicolas Casiez, Thierry Chevolleau, Geraud Dubois, Willi Volksen, Theo J Frot, Romain Hurand, Thibaut L David, Nicolas Posseme, Nevine Rochat, others
Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures 31(1), 011207--011207, AVS, 2013


2012

Integration of a Manufacturing Grade, k= 2.0 Spin-On Material in a Single Damascene Structure
Willi Volksen, Sampath Purushothaman, Maxime Darnon, Mike F Lofaro, Stephan A Cohen, James P Doyle, Nicholas Fuller, Teddie P Magbitang, Philip M Rice, Leslie E Krupp, others
ECS Journal of Solid State Science and Technology 1(5), N85--N90, The Electrochemical Society, 2012

Atmospheric Plasma Deposited Dense Silica Coatings on Plastics
Linying Cui, Alpana N Ranade, Marvi A Matos, Liam S Pingree, Theo J Frot, Geraud Dubois, Reinhold H Dauskardt
ACS applied materials \& interfaces 4(12), 6587--6598, ACS Publications, 2012

Low-k Materials: Recent Advances
G. Dubois, W. Volksen
Advanced Interconnects for ULSI Technology, 1--33, Wiley Online Library, 2012

Moisture-Insensitive Polycarbosilane Films with Superior Mechanical Properties
Y. Matsuda, JS Rathore, LV Interrante, RH Dauskardt, G. Dubois
ACS Applied Materials & Interfaces 4(5), 2659-2663, American Chemical Society, 2012

Post Porosity Plasma Protection: Scaling of Efficiency with Porosity
Theo Frot, Willi Volksen, Sampath Purushothaman, Robert L. Bruce, Teddie Magbitang, Dolores C. Miller, Vaughn R. Deline, Geraud Dubois
Advanced Functional Materials 22(14), 3043-3050, 2012


2011

Post-Porosity Plasma Protection: A New Platform to Integrate k < 2.4 Ultra Low-k Materials
T. Frot, W. Volksen, T. Magbitang, S. Purushothaman, R. Bruce, S. Cohen, M. Lofaro, G. Dubois
Future Fab International 39, 2011

A Manufacturing Grade, Porous Oxycarbosilane Spin-On Dielectric Candidate with K≤ 2.0
W. Volksen, T.P. Magbitang, R.D. Miller, S. Purushothaman, S.A. Cohen, H. Nakagawa, Y. Nobe, T. Kokubo, G.J.M. Dubois
Journal of the Electrochemical Society158, G155, 2011

Planar Collimated Illumination System Using Nano-Hybrid Low Index Materials
Y. Taira, H. Numata, G. Dubois, W. Volksen
Frontiers in Optics, 2011

Future of PECVD and spin-on ultra low-k materials
W Volksen, T Frot, T Magbitang, S Gates, Mark Oliver, R Dauskardt, G Dubois
Interconnect Technology Conference and 2011 Materials for Advanced Metallization (IITC/MAM), 2011 IEEE International, pp. 1--3

Post Porosity Plasma Protection a new approach to integrate k≤ 2.2 porous ULK materials
T. Frot, W. Volksen, T. Magbitang, D. Miller, S. Purushothaman, M. Lofaro, R. Bruce, G. Dubois
Interconnect Technology Conference and 2011 Materials for Advanced Metallization (IITC/MAM), 2011 IEEE International, pp. 1--3

Application of the Protection/Deprotection Strategy to the Science of Porous Materials
Theo Frot, Willi Volksen, Sampath Purushothaman, Robert Bruce, Geraud Dubois
Advanced Materials 23(25), 2828-+, 2011

Cryogenic plasmas for controlled processing of nanoporous materials
F. Iacopi, J.H. Choi, K. Terashima, P.M. Rice, G. Dubois
Physical Chemistry Chemical Physics 13(9), 3634--3637, Royal Society of Chemistry, 2011


2010

Molecular design of ultra-low-k hybrid glasses
M. Oliver, G. Dubois, R. Dauskardt
Interconnect Technology Conference (IITC), 2010 International, pp. 1--3

Low dielectric constant materials
W. Volksen, R.D. Miller, G. Dubois
Chemical reviews 110(1), 56, 2010

Molecular origins of the mechanical behavior of hybrid glasses
M.S. Oliver, G. Dubois, M. Sherwood, D.M. Gage, R.H. Dauskardt
Advanced Functional Materials 20(17), 2884--2892, Wiley Online Library, 2010


2009

Adjusting the skeleton and pore structure of porous SiCOH dielectrics
SM Gates, G. Dubois, ET Ryan, A. Grill, M. Liu, D. Gidley
Journal of the Electrochemical Society156, G156, 2009


2008

Mechanical enhancement of low-k organosilicates by laser spike annealing
W. Volksen, G. Dubois, A. Kellock, T.P. Magbitang, R.D. Miller, D. Miller, S. Cohen, E.E. Simonyi, L. Ramirez, D. Markle, others
Journal of the Electrochemical Society155, G224, 2008

Organic Thin Film Transistor Using a Photo-Curable Organic/Inorganic Hybrid Material as a Gate Dielectric
D.H. Hwang, Y.S. Yang, J.I. Lee, S.H. Kim, O.H. Park, H.C. Kim, V. Lee, G. Dubois, R.D. Miller
Journal of Nanoscience and Nanotechnology 8(9), 4561--4564, American Scientific Publishers, 2008

Molecular-Controlled Fracture and Release of Templated Nanoporous Organosilicate Thin Films
M.D. Ong, W. Volksen, G. Dubois, V. Lee, P.J. Brock, V.R. Deline, R.D. Miller, R.H. Dauskardt
Advanced Materials 20(16), 3159--3164, Wiley Online Library, 2008

Ultra Low-k Films Derived from Hyperbranched Polycarbosilanes (HBPCS)
J.S. Rathore, L.V. Interrante, G. Dubois
Advanced Functional Materials 18(24), 4022--4028, Wiley Online Library, 2008

Superior mechanical properties of dense and porous organic/inorganic hybrid thin films
G. Dubois, W. Volksen, T. Magbitang, M.H. Sherwood, R.D. Miller, D.M. Gage, R.H. Dauskardt
Journal of Sol-Gel Science and Technology 48(1), 187--193, Springer, 2008


2007

Impact of curing kinetics and materials properties on imprint characteristics of resists for UV nano-imprint lithography
Frances A Houle, Ann Fornof, Ratnam Sooriyakumaran, Hoa Truong, Dolores C Miller, Martha I Sanchez, Blake Davis, Teddie Magbitang, Robert D Allen, Mark W Hart, others
Advanced Lithography, pp. 65191C--65191C, 2007

Dielectric Films for Advanced Microelectronics
G. Dubois, RD Miller, W. Volksen, MR Baklanov, M. Green, K. Maex
2007 - Wiley New York, Wiley New York

Spin‐on Dielectric Materials
G. Dubois, R.D. Miller, W. Volksen
Dielectric films for advanced microelectronics, 33--83, Wiley Online Library, 2007

Microelectronic Materials with Hierarchical Organization
G. Dubois, RD Miller, J.L. Hedrick
Macromolecular Engineering, 2331--2367, Wiley Online Library, 2007

Site isolation and epoxidation reactivity of a templated ferrous bis (phenanthroline) site in porous silica
T.J. Terry, G. Dubois, A. Murphy, T.D.P. Stack
Angewandte Chemie 119(6), 963--965, Wiley Online Library, 2007

Molecular network reinforcement of sol--gel glasses
G. Dubois, W. Volksen, T. Magbitang, R.D. Miller, D.M. Gage, R.H. Dauskardt
Advanced Materials 19(22), 3989--3994, Wiley Online Library, 2007


2006

Analysis of Plasma-Induced Modification of ULK and eULK Materials: Dual Damascene Processing Challenges for 45nm (K⩽ 2.4) and Beyond BEOL Technologies
NCM Fuller, MA Worsley, S Nitta, T Dalton, TL Tai, S Bent, T Magbitang, G Dubois, R Miller, W Volksen, others
Interconnect Technology Conference, 2006 International, pp. 24--26

Imaging thin films of nanoporous low-k dielectrics: comparison between ultramicrotomy and focused ion beam preparations for transmission electron microscopy
Leslie E Thompson, Philip M Rice, Eugene Delenia, Victor Y Lee, Phillip J Brock, Teddie P Magbitang, Geraud Dubois, Willi Volksen, Robert D Miller, Ho-Cheol Kim
Microscopy and Microanalysis 12(02), 156--159, Cambridge Univ Press, 2006

Laser spike annealing: a novel post-porosity treatment for significant toughening of low-k organosilicates
W. Volksen, G. Dubois, A. Kellock, T.P. Magbitang, R.D. Miller, S. Cohen, E.E. Simonyi, L. Ramirez, Y. Wang
Interconnect Technology Conference, 2006 International, pp. 146--148

Monolayered organosilicate toroids and related structures: A phase diagram for templating from block copolymers
J. Choi, T.M. Hermans, B.G.G. Lohmeijer, R.C. Pratt, G. Dubois, J. Frommer, R.M. Waymouth, J.L. Hedrick
Nano letters 6(8), 1761--1764, ACS Publications, 2006

Organocatalytic Living Ring-Opening Polymerization of Cyclic Carbosiloxanes
Lohmeijer, Bas G. G.; Dubois, Geraud; Leibfarth, Frank; Pratt, Russell C.; Nederberg, Fredrik; Nelson, Alshakim; Waymouth, Robert M.; Wade, Charles; Hedrick, James L.
Org. Lett. 8(21), 4683, ACS Publications, 2006

Application of Solvent-Directed Assembly of Block Copolymers to the Synthesis of Nanostructured Materials with Low Dielectric Constants
T.M. Hermans, J. Choi, B.G.G. Lohmeijer, G. Dubois, R.C. Pratt, H.C. Kim, R.M. Waymouth, J.L. Hedrick
Angewandte Chemie International Edition 45(40), 6648--6652, Wiley Online Library, 2006


2005

Structure of dioxygen binding xerogels incorporating cyclams complexed with CuCl2 salts
C. Goulon-Ginet, J. Goulon, A. Rogalev, F. Wilhelm, N. Jaouen, G. Dubois, S. Brand`es, G. David, R. Guilard, R. Corriu, others
Physica Scripta2005, 681, IOP Publishing

Dekker Encyclopedia of Nanoscience and Nanotechnology
H.C. Kim, G. Dubois
2005 - Taylor & Francis, Taylor \& Francis

A Study Using X-ray Absorption and Emission Spectroscopy of Dioxygen-Binding Xerogels Incorporating Cyclam Units Complexed with Copper Salts
J. Goulon, C. Goulon-Ginet, A. Rogalev, F. Wilhelm, N. Jaouen, D. Cabaret, Y. Joly, G. Dubois, R.J.P. Corriu, G. David, others
European journal of inorganic chemistry 2005(13), 2714--2726, Wiley Online Library

Oriented Nanoporous Lamellar Organosilicates Templated from Topologically Unsymmetrical Dendritic‐Linear Block Copolymers
T. Magbitang, V.Y. Lee, J.N. Cha, H.L. Wang, W.R. Chung, R.D. Miller, G. Dubois, W. Volksen, H.C. Kim, J.L. Hedrick
Angewandte Chemie International Edition 44(46), 7574--7580, Wiley Online Library, 2005


2004

Templating Organosilicate Vitrification Using Unimolecular Self-Organizing Polymers Prepared from Tandem Ring Opening and Atom Transfer Radical Polymerizations
T. Magbitang, VY Lee, EF Connor, LK Sundberg, H.C. Kim, W. Volksen, CJ Hawker, RD Miller, JL Hedrick
Macromolecular Symposia, pp. 295--306, 2004

Metallocorroles as sensing components for gas sensors: remarkable affinity and selectivity of cobalt (III) corroles for CO vs. O2 and N2
J.M. Barbe, G. Canard, S. Brand`es, F. J'er^ome, G. Dubois, R. Guilard
Dalton Trans. pp. 8, 1208--1214, The Royal Society of Chemistry, 2004


2003

Versatile synthesis of nanometer sized hollow silica spheres
J.J.L.M. Cornelissen, E.F. Connor, H.C. Kim, V.Y. Lee, T. Magibitang, P.M. Rice, W. Volksen, L.K. Sundberg, R.D. Miller
Chemical Communications 45(8), 1010--1011, Royal Society of Chemistry, 2003

Simple iron catalyst for terminal alkene epoxidation
G. Dubois, A. Murphy, T.D.P. Stack
Organic Letters 5(14), 2469--2472, ACS Publications, 2003

Efficient epoxidation of electron-deficient olefins with a cationic manganese complex
A. Murphy, G. Dubois, TDP Stack
Journal of the American Chemical Society 125(18), 5250--5251, ACS Publications, 2003


2002

Cyclam complexes containing silica gels for dioxygen adsorption
G. Dubois, R. Tripier, S. Brand`es, F. Denat, R. Guilard
J. Mater. Chem. 12(8), 2255--2261, The Royal Society of Chemistry, 2002


2001

Silica Gel Bound Cyclam. Synthesis and Applications
F. Denat, G. Dubois, R. Tripier, S. Brandes, R. Guilard
2001 - Taylor & Francis, Taylor \& Francis

Coordination Chemistry in the Solid: Study of the Incorporation of CuII into Cyclam-Containing Hybrid Materials
G. Dubois, C. Rey'e, R.J.P. Corriu, S. Brand`es, F. Denat, R. Guilard
Angewandte Chemie 113(6), 1121--1124, Wiley Online Library, 2001


2000

Organic--inorganic hybrid materials. Preparation and properties of dibenzo-18-crown-6 ether-bridged polysilsesquioxanes
G. Dubois, C. Rey'e, R.J.P. Corriu, C. Chuit
J. Mater. Chem. 10(5), 1091--1098, The Royal Society of Chemistry, 2000


1999

First organic--inorganic hybrid materials with controlled porosity incorporating cyclam units
G. Dubois, R.J.P. Corriu, C. Rey'e, S. Brand`es, F. Denat, R. Guilard
Chem. Commun. pp. 22, 2283--2284, The Royal Society of Chemistry, 1999

Hybrid organic--inorganic materials. Preparation and properties of dibenzo-18-crown-6 ether-bridged polysilsesquioxanes
C. Chuit, R.J.P. Corriu, G. Dubois, C. Rey'e
Chem. Commun. pp. 8, 723--724, The Royal Society of Chemistry, 1999