J. Pacansky, H. Coufal
Journal of Molecular Structure
A photochemical method is presented with which a large number of nitrile-HCN complexes and nitrile dimers may be selectively produced for spectroscopic analysis. The method consists of isolating suitable tetrazine systems in low-temperature matrices. Subsequently, the matrix is irradiated with UV light to produce the desired nitrile-HCN complex or the nitrile dimer. This is demonstrated by presenting the infrared spectra of the benzonitrile-HCN complex and the acetonitrile dimer which were generated photochemically from monophenyltetrazine and 1,4-dimethyltetrazine. © 1980 American Chemical Society.
J. Pacansky, H. Coufal
Journal of Molecular Structure
George W. Tyndall, R.J. Waltman, et al.
Journal of Applied Physics
J. Pacansky, H. Coufal, et al.
Journal of Photochemistry
J. Pacansky, R.J. Waltman
Chemistry of Materials