Journal of Physical Chemistry

Paper

01 May 2002

Determination of the signs of the fluorine hyperfine coupling constants of monosubstituted benzyl radicals

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Abstract

The signs of the fluorine hyperfine coupling constants of monosubstituted benzyl radicals have been determined by CIDNP studies of fluorobenzyl phenyl ketones. The para and ortho couplings are found to be positive whereas the meta. coupling is negative.

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