O.F. Schirmer, K.W. Blazey, et al.
Physical Review B
Ligand-stabilized copper(I) hexafluoroacetylacetonate complexes display varying degrees of stability to oxidation and thermal decomposition. In an effort to understand the nature of the copper-alkene bond in these complexes better, 1H and 13C nuclear magnetic resonance spectra were obtained and compared to the spectra of the free alkene. In accord with Dewar-Chatt-Duncanson theory, the extent of π and σ bonding contributions can be qualitatively determined by the observed chemical shift changes upon complexation of the alkene to the copper(I) center. © 1992.
O.F. Schirmer, K.W. Blazey, et al.
Physical Review B
B.A. Hutchins, T.N. Rhodin, et al.
Surface Science
J.H. Stathis, R. Bolam, et al.
INFOS 2005
Andreas C. Cangellaris, Karen M. Coperich, et al.
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