Journal of Electron Spectroscopy and Related Phenomena

Paper

01 Jan 1987

Vibrational and electronic properties of cyanide adsorbed on metal electrodes

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Abstract

The origin of the potential dependence of the high vibration frequency vCN is explained as a Stark effect. It is shown by means of ab initio cluster calculations that the coupling of vCN to the low frequency metal-ligand stretch plays a crucial role. © 1987.

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